Phil, it all depends wich kit you go for. some kits need to be controlled from and ECU, some don't.
the simpliest kits just switch on WI pump when a certain boost is reached (0.7 bar for exemple). This is a very simple way of working you will get more water/meth close to peak torque region, wich is were you will need it the most anyway.
Aquamist 1S
then you have progressive kit, that can vary the pump speed to vary the flow. I'm not realy fan of the low entry Progressive kits as the flow won't be constant anyway.
Only exeption to this was the PERRIN kit as it was using an aquamist Racepump intead of the comonly used shulfo pump progressive kits.
Then you have high speed valves kits that pulse the flow pretty much like an injector do. Aquamist offers kits using this system. some of this kits will just read from one of your fuel injector and copy its flow. those are my favorites system. both HFS-5 and PERRIN kit are working this way. the difference is the PERRIN use a RacePump with no highspeed valve, while the HSF-5 use a shulfo pump with high speed valve. HSF-5 has faster response and wider flow range.
If cooling down is your main concern, you can place nozzle just before IC, this will get your temp the lowest you can. now the closest your nozzle are to combustion chamber, the most reactive it will be... you could also place two smaler nozzles, one just before IC, then an other one just before throttle body
Some guys place nozzle just in front of turbo, but Munday explained it has some downsides I wouldn't risk
I've just been confirmed PERRIN PWI-1 has just been discontinued, but some kits are still available in online shops, might be time to grab one while you still can
Fur, are you using Aquamist 2D by any chance ?